Angelina Jolie coveted Jennifer Aniston's husband in 2005, and now it seems as if the 36-year-old is envious of her sexy wardrobe, too.

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The In the Land of Blood and Honey director struck an out-of-character and over-the-top pose while modeling her custom Atelier Versace gown at the 84th Annual Academy Awards. "I wanted to be comfortable and I feel sexy in black velvet," Jolie told Us Weekly on the red carpet.

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Jolie completed her look with Neil Lane jewelry, Salvatore Ferragamo peep-toe heels and a Jaime Mascaro clutch. Her partner, Brad Pitt, 48, wore a Tom Ford tuxedo.

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Jolie's vampy look evoked memories of Aniston, now 43, at the 2010 Golden Globes. The Wanderlust actress topped numerous best-dressed lists that year when she wore a high-slit Valentino dress, Versace shoes and Fred Leighton jewelry.

Tell Us: Did Angelina Jolie copy her rival Jennifer Aniston's leg-baring style?

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