Katie Holmes, Blake Lively Look Sexy, Bond at 12-12-12 Concert

USMagazine, Thursday, December 13, 2012, 6:45am (PST)

Lots to catch up on!

They're two of this year's most talked-about Hollywood women, and at Wednesday night's star-studded 12-12-12: A Concert for Sandy Relief at NYC's Madison Square Garden, Katie Holmes and Blake Lively encountered one another backstage.

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Recently divorced from Tom Cruise, 33-year-old Holmes appeared for the charity event in one of her sexiest looks to date: A curve-hugging purple velvet dress by Tom Ford featuring daring panels, plus "Padlock" pump by the same designer. Currently starring in Broadway comedy Dead Accounts, the mom to 6-year-old Suri wore her brunette locks down in loose waves.

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25-year-old Lively, meanwhile, lent her support at the event in one of her first major events since she wed  Ryan Reynolds in a surprise, top-secret bash back in September. The fashionista wore a tight, studded red leather mini-dress by Isabel Marant and nude caged ankle boots by Christian Louboutin.

Just a few nights ago, former Dawson's Creek star Holmes celebrated the holiday season at Broadway Dreams Foundation's Champagne and Caroling gala -- where she was spotted "double-fisting champagne in one hand with a Diet Coke in one hand with a Diet Coke in the other."

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Lively, whose Gossip Girl airs its last-ever episode next Tuesday Dec. 18, has been keeping an especially low profile since since and Reynolds, 36, tied the knot. The blissed-out couple were photographed packing on the PDA Dec. 3 on the Pont des Arts bridge in Paris.

"The locals said hello, but they were only interested in each other," an eyewitness told Us.

This article originally appeared on Katie Holmes, Blake Lively Look Sexy, Bond at 12-12-12 Concert

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