It's Mrs. Timberlake!

On Sunday, Jessica Biel was photographed on her own for the first time since she and Justin Timberlake exchanged their marital vows on Friday, Oct. 19.

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Stepping out at the Borgo Egnazia resort in Fasano, Italy -- where 150 loved ones watch the couple become husband and wife -- the Valentine's Day actress, 30, looked radiant and casual in jeans, an off-the-shoulder white shirt and sunglasses, with her hair in a loose, sexy bun.

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Biel was also wearing, of course, her brand-new new wedding band, which she paired with the gigantic engagement ring she's been rocking for nearly a year.

With guests like Andy Samberg, music manager Johnny Wright and Seventh Heaven's Beverley Mitchell looking on, Biel and Timberlake, 31, exchanged vows in the hotel's chapel -- walking down a grand staircase where they were showered with small, white, heart-shaped flower petals.

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Timberlake was photographed solo on Saturday, flashing his own brand-new gold wedding band to photographers.

This article originally appeared on Usmagazine.com: PICTURE: Jessica Biel Steps Out Solo Post-Wedding -- See Her Ring!