There was a telltale sign that this relationship was doomed years before they attended their last Academy Awards ceremony together. When the married couple was presenting an Oscar in 2002, Ryan told his wife to open the winning envelope, saying, "You make more money than I do. Go ahead!" The couple stuck it out a little longer and Reese even thanked Ryan when she won the Best Actress trophy in 2006. But less than a year later this duo was dunzo.