Like Seth Green, Marsters embraced geek culture in a big way, following up "Angel" with turns on "Smallville," "Caprica," and "Torchwood" and as the big bad in the movie "Dragonball Evolution." He also appeared on "Supernatural" opposite Charisma Carpenter. Outside of acting, he's pursued his musical inclinations, offering lead vocals in 2003 and 2004 to the band Ghost of the Robot and releasing solo albums in 2004 and 2007. Marsters wed his second wife, German fashion designer Patricia Rahman, in January 2011. And yes, he stopped bleaching his hair.