An elevator incident that almost eclipses Solange-Gate! Pat O'Brien claims in his memoir "I'll Be Right Back After This" that Angelina Jolie once told him in an elevator that she was "really horny" and on a man hunt after splitting from Billy Bob Thornton in 2002.

PHOTOS: Angelina's transformation

In a snippet of the tell-all, obtained by the Daily Mail, the former "Access Hollywood" host claims the elevator run-in with Jolie occurred over a decade ago at Beverly Hills hotel L'Ermitage. "I said, 'What's up baby?' O'Brien recalled of bumping into the Oscar winner. Jolie's response? "I'm trying to find this guy I kind of know because I'm really horny right now.'" Seemingly unfazed, O'Brien writes, "I joked that she had my number and we laughed."

PHOTOS: Brad and Angelina

Aside from that reportedly amazing moment, the memoir also details the time Jolie's dad Jon Voight pleaded to O'Brien, during an interview with Access Hollywood in 2002, for his estranged daughter to seek help for her "serious mental problems."

PHOTOS: Angelina's Us Weekly covers

The TV host says Voight told him during a coffee meeting, "I want to talk to you about my daughter. I'm brokenhearted. That's the reason I'm here. I feel I can trust you as a journalist."

O'Brien's book, which is available now, also touches upon his past substance abuse issues.


BING: Celebs banned from countries

Angelina Jolie, Vin Diesel and more red carpet showoffs

Jennifer Lopez, Beyonce and more of Hollywood's hottest moms