On the 1994 set of their film "Se7en," Gwyneth connected with her on-screen husband Brad Pitt. The cameras eventually stopped rolling, but their love affair kept right on trucking. Her relationship with Brad, then People magazine's reigning Sexiest Man Alive, thrust a 23-year-old Gwyneth into the spotlight -- and the headlines. In April 1995, the duo were snapped sunbathing nude while vacationing in St. Barts. Brad ultimately won an invasion-of-privacy suit against the offending photographer, but the public fascination with the couple had only just begun. On Jan. 21, 1996, Brad accepted the Golden Globe for Best Supporting Actor for his role in "12 Monkeys." He gave a shout-out to his girlfriend of a year during his acceptance speech, calling her "the love of my life, my angel." That same year, Gwyneth told You magazine, "I am properly in love for the first time in my life, and I do not care if my former boyfriends read this."