- Photo: Gina James/Retna Ltd.2 of 13
Who: Jonny Lee Miller
What: Was married to Angelina, 1996-1999
After meeting Miller on the set of the 1996 film "Hackers," Angelina chose him as husband No. 1. According to a New York Times article, Jolie's wedding ensemble included "black rubber pants and a white shirt with the groom's name written in blood across the back." They remained friends after their divorce.